Unprecedented Low Cu−N(azide)−Cu Angles in End-On Double Azido Bridged Copper(II) Complex
收藏NIAID Data Ecosystem2026-03-06 收录
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A rare asymmetric end-on double azido-bridged copper(II) complex has been synthesized and characterized structurally and magnetically. The Cu−N(azide)−Cu angle in this complex is calculated to be 89.1°. This is unusually low in comparison to the same angle in other end-on azido-bridged binuclear complexes reported so far. Though a strong ferromagnetic interaction between the metal centers is expected in the complex, the coupling has actually been found to be antiferromagnetic, instead.
创建时间：
2016-05-07
