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Luminescent Heteroleptic Tris(dipyrrinato)indium(III) Complexes

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https://figshare.com/articles/dataset/Luminescent_Heteroleptic_Tris_dipyrrinato_indium_III_Complexes/2308603
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资源简介:
To provide an improvement over the low fluorescence efficiencies often shown by homoleptic tris­(dipyrrinato)­indium­(III) complexes, luminescent heteroleptic tris­(dipyrrinato)­indium­(III) complexes bearing two types of dipyrrinato ligands are designed here by theoretical calculation and then synthesized. They possess frontier orbitals linked to suppression of the nonemissive charge-separated states; one shows a high fluorescence quantum yield (0.41) in toluene, which exceeds that of the corresponding BF2 complex.
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2016-02-17
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