Luminescent Heteroleptic Tris(dipyrrinato)indium(III) Complexes
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https://figshare.com/articles/dataset/Luminescent_Heteroleptic_Tris_dipyrrinato_indium_III_Complexes/2308603
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资源简介:
To provide an improvement over the
low fluorescence efficiencies often shown by homoleptic tris(dipyrrinato)indium(III)
complexes, luminescent heteroleptic tris(dipyrrinato)indium(III) complexes
bearing two types of dipyrrinato ligands are designed here by theoretical
calculation and then synthesized. They possess frontier orbitals linked
to suppression of the nonemissive charge-separated states; one shows
a high fluorescence quantum yield (0.41) in toluene, which exceeds
that of the corresponding BF2 complex.
创建时间:
2016-02-17



