Synthesis of Carbamoyl Azides from Primary Amines and Carbon Dioxide under Mild Conditions
收藏NIAID Data Ecosystem2026-03-06 收录
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Treatment of amines under a carbon dioxide atmosphere with tetramethylphenylguanidine (PhTMG) and diphenylphosphoryl azide (DPPA) in acetonitrile below 0 °C provides carbamoyl azides in high to excellent yields. In addition, epimerization is not observed when optically pure α-amino esters are used as substrates.
创建时间：
2016-06-03
