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Enantioselective Total Synthesis of (−)-Nardoaristolone B via a Gold(I)-Catalyzed Oxidative Cyclization

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NIAID Data Ecosystem2026-03-09 收录
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https://figshare.com/articles/dataset/Enantioselective_Total_Synthesis_of_Nardoaristolone_B_via_a_Gold_I_Catalyzed_Oxidative_Cyclization/2047950
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The first enantioselective total synthesis of (−)-nardoaristolone B is accomplished by the implementation of an enantio- and diastereoselective copper­(I)-catalyzed conjugate addition/enolate trapping sequence and a gold­(I)-catalyzed oxidative cyclization (intermolecular oxidant), employed for the first time in total synthesis.
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2015-12-17
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