Aromatic Macrocycle Containing Amine and Imine Groups: Intramolecular Charge-Transfer and Multiple Redox Behavior
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https://figshare.com/articles/dataset/Aromatic_Macrocycle_Containing_Amine_and_Imine_Groups_Intramolecular_Charge_Transfer_and_Multiple_Redox_Behavior/2582056
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资源简介：
A cyclic compound that has alternating diphenylamine
and quinodiimine
units was obtained by condensation of anthraquinone with bis(4-aminophenyl)amine
(aniline dimer) in 20% yield. The resulting macrocycle has an absorption
of 462 nm, which is assigned to charge transfer transitions between
electron-rich diphenylamine units and electron-poor anthraquinone
diimine units. Cyclic voltammetry in acidic MeCN shows redox of anthraquinone
diimine units (E1/2 = 0.03 V vs Ag/Ag+) and of oxidation of amino groups of higher potentials (0.60
and 0.77 V).
创建时间：
2016-02-22
