A Golden Ring: Molecular Gold Carbido Complexes
收藏Figshare2016-02-19 更新2026-04-29 收录
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https://figshare.com/articles/dataset/A_Golden_Ring_Molecular_Gold_Carbido_Complexes/2428861
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Stannylcarbynes [M(CSnMe3)(CO)2(Tp*)] [M = Mo, W; Tp* = hydrotris(dimethylpyrazol-1-yl)borate], which are readily obtained via the successive treatment of [M(CBr)(CO)2(Tp*)] with nBuLi and ClSnMe3, serve as effective carbyne transmetalation agents for the preparation of heteronuclear molecular gold carbido complexes such as [M(CAuPPh3)(CO)2(Tp*)] and the tetrameric golden ring complex [W(CAu)(CO)2(Tp*)]4, which are in turn able to transfer the carbido unit to palladium.
创建时间：
2016-02-19
