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Asymmetric Direct Aldol Reactions of Acetoacetals Catalyzed by a Simple Chiral Primary Amine

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https://figshare.com/articles/dataset/Asymmetric_Direct_Aldol_Reactions_of_Acetoacetals_Catalyzed_by_a_Simple_Chiral_Primary_Amine/2805565
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资源简介:
An asymmetric direct aldol reaction of acetoacetals is described. Under the catalysis of a simple chiral primary amine, the direct aldol reactions of acetoacetals occur exclusively on the γ-position to give vinylogous-type aldol products with high diastereo- and enantioselectivity.
创建时间:
2016-02-25
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