Polygermane Building Blocks
收藏NIAID Data Ecosystem2026-03-06 收录
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https://figshare.com/articles/dataset/Polygermane_Building_Blocks/2715343
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资源简介：
Tetrakis(trimethylgermyl)germane was prepared by the reaction of
chlorotrimethylgermane and tetrabromogermane with lithium at −78
°C. Reaction with potassium tert-butoxide/18-crown-6
gave (Me3Ge)3GeK·18-crown-6, which displayed
typical reactivity with electrophiles. In the reaction of (Me3Ge)3GeSiMe3 with tert-butoxide/18-crown-6 exclusive attack at the trimethylsilyl group
was observed. Attempts to obtain a dimetalated species from (Me3Ge)3GeGe(GeMe3)3 and 2 tert-butoxide/2 18-crown-6 failed due to cleavage of the
central Ge−Ge bond. The respective dianion was, however, accessible
employing (Me3Si)(Me3Ge)2GeGe(GeMe3)2(SiMe3) as the precursor.
创建时间：
2010-11-08
