One-Dimensional Indium Sulfides with Transition Metal Complexes of Polyamines
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https://figshare.com/articles/dataset/One_Dimensional_Indium_Sulfides_with_Transition_Metal_Complexes_of_Polyamines/2992348
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资源简介：
Three new indium sulfides, [Ni(dien)2]0.5[InS2] (dien = diethylenetriamine) (1), [Ni(dap)3]0.5[InS2] (dap =
1,2-diaminopropane) (2), and [Ni(tepa)]2[In4S7(SH)2]·H2O (tepa = tetraethylenepentamine) (3), have been prepared
under solvothermal conditions and characterized by single-crystal X-ray diffraction. Compounds 1 and 2 consist of
discrete 1-D {[InS2]-} ∞ chains with complex cations as charge-compensating ions, while compound 3 consists of
a novel 1-D anionic chain constructed from arachno-shaped In4S11 clusters. The sulfide chain of 3 coordinates into
the complex cations via the nonterminal S atoms of the polymeric anion, forming a covalently linked organic−inorganic hybrid compound.
创建时间：
2016-02-28
