Pd-Catalyzed Enantioselective Syntheses of Trisubstituted Allenes via Coupling of Propargylic Benzoates with Organoboronic Acids
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https://figshare.com/articles/dataset/Pd-Catalyzed_Enantioselective_Syntheses_of_Trisubstituted_Allenes_via_Coupling_of_Propargylic_Benzoates_with_Organoboronic_Acids/12301496
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资源简介：
Enabled
by the newly developed ligand, Ming-Phos, the first example
of palladium-catalyzed highly enantioselective coupling of racemic
propargylic benzoates with organoboronic acids for chiral allenes
synthesis has been developed. Excellent asymmetric induction has been
achieved with a decent substrate scope. Synthetic potentials for the
construction of polycyclic compounds with multiple chiral centers
have been demonstrated.
创建时间：
2020-04-25
