Organometallic Macrocyclic Chemistry. 8. An Unusual Metallacycle Derived from Phosphine−Alkynyl Thioether Coupling
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https://figshare.com/articles/dataset/Organometallic_Macrocyclic_Chemistry_8_An_Unusual_Metallacycle_Derived_from_Phosphine_Alkynyl_Thioether_Coupling/2705863
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资源简介：
The α,ω-diyne 4,7,10-trithiatrideca-2,11-diyne reacts with [RuCl2(PPh3)3] and KPF6 to form the phosphonio-substituted metallatricyclic salt [RuCl(PPh3){κ4C,S,S′,S′′-S(CCMe)C2H4SC2H4SC(PPh3)CMe}]PF6 arising from the activation of one alkynyl group toward nucleophilic attack by extraneous phosphine.
创建时间：
2010-12-13
