Polyoxomolybdate-Calix[4]arene Hybrid: A Catalyst for Sulfoxidation Reactions with Hydrogen Peroxide
收藏Figshare2016-02-12 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Polyoxomolybdate_Calix_4_arene_Hybrid_A_Catalyst_for_Sulfoxidation_Reactions_with_Hydrogen_Peroxide/2121145
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An easily accessible polyoxomolybdate–calix[4]arene hybrid 1 has been synthesized and applied as a heterogeneous catalyst in the sulfoxidation of thioethers to sulfoxides and to sulfones under strictly stoichiometric amounts of 30% H2O2 in CH3CN as the solvent. This study represents the first promising example of successful employment of calixarenes–polyoxometalate (POM) hybrid materials in the area of catalytic oxidations.
创建时间:
2016-02-12



