Guanylation of Amines Catalyzed by a Half-Sandwich Titanacarborane Amide Complex
收藏NIAID Data Ecosystem2026-03-06 收录
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https://figshare.com/articles/dataset/Guanylation_of_Amines_Catalyzed_by_a_Half_Sandwich_Titanacarborane_Amide_Complex/3049762
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资源简介：
This work describes a new atom-economical catalytic
process for the guanylation of amines with a broad substrate
scope using the half-sandwich titanacarborane amide [σ:η1:η5-(OCH2)(Me2NCH2)(C2B9H9)]Ti(NMe2) as catalyst. This species bears two different sidearms: one is strongly bonded to
the Ti center by taking the advantage of its high oxophilicity,
whereas the other is hemilabile in nature, binding the Ti center
reversibly.
创建时间：
2016-02-29
