Participation of the α,α‘-Diiminopyridine Ligand System in Reduction of the Metal Center during Alkylation
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https://figshare.com/articles/dataset/Participation_of_the__-Diiminopyridine_Ligand_System_in_Reduction_of_the_Metal_Center_during_Alkylation/3641004
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资源简介：
The reaction of {[2,6-(i-Pr)2PhNC(Me)]2(C5H3N)}MnCl2 with alkylating agents formed a dinuclear
Mn(I) derivative via ligand reductive coupling. In the case of the trivalent Cr analogue, a similar reaction
afforded reduction toward Cr(II) but also alkylation at the pyridine ring para position followed by an
unprecedented cycloaddition that generated a tricyclic system.
创建时间：
2016-08-18
