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Pushing the Frontiers of Hard and Soft Scorpionate Chemistry

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https://figshare.com/articles/dataset/Pushing_the_Frontiers_of_Hard_and_Soft_Scorpionate_Chemistry/3352207
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The preparation and structure of the first scorpionate complex of a group 16 element, [Te(κ2-TmMe)2], is reported. It displays square planar geometry at the Te atom and two distinct ligand conformations. In addition, the first pyrazolylborate complex of a group 15 element, [Bi(Tp)2(pzH)Cl], has been synthesized and characterized.
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2004-01-26
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