**This data set has been superseded by DOI: https://doi.org/10.5523/bris.3epws48ek1oyb217so2fzwr3cv** Extended data set for the study reported in Lewandowsky, S., Oberauer, K., & Gignac, G. E. (
A systematic study of the opening of a collection of chlorinated vinyl epoxides is reported, which includes experiments that implicate both five- and four-membered chloronium ions as plausible interme
The cyclohexa-2,5-dien-1-yl group is established as a leaving group at silicon as an alternative to the Bartlett–Condon–Schneider silicon-to-carbon hydride transfer and the allyl-leaving-group approac
