Synthesis of the Scalarane Sesterterpenoid 16-deacetoxy-12-epi-scalarafuranacetate
收藏Figshare2016-02-23 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Synthesis_of_the_Scalarane_Sesterterpenoid_16_deacetoxy_12_i_epi_i_scalarafuranacetate/2617921
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The marine natural product 16-deacetoxy-12-epi-scalarafuranacetate, isolated from Spongua officinalis, was synthesized in 18 linear steps, starting from (−)-sclareol, with high stereoselectivity and an overall yield of 6.1%. The intermediate 16-deacetoxy-12-epi-scalarafuran could be easily transformed into a series of natural scalarane sesterterpenoids in a few steps.
创建时间:
2016-02-23



