Heterometallic Metal–Organic Frameworks That Catalyze Two Different Reactions Sequentially
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https://figshare.com/articles/dataset/Heterometallic_Metal_Organic_Frameworks_That_Catalyze_Two_Different_Reactions_Sequentially/3406153
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资源简介：
A series of copper-
and alkaline-earth-metal-based multidimensional
metal–organic frameworks, {[CuMg(pdc)2(H2O)4]·2H2O}n (1), [CuCa(pdc)2]n (2), [CuSr(pdc)2(H2O)3]n (3), and {[CuBa(pdc)2(H2O)5]·H2O}n (4), where H2Pdc = pyridine-2,5-dicarboxylic
acid, were hydrothermally synthesized and characterized. Two different
metals act as the active center to catalyze two kinds of reactions,
viz., olefin to its epoxide followed by epoxide ring opening to afford
the corresponding vicinal diol in a sequential manner.
创建时间：
2016-06-14
