Dinuclear NHC Gold(I) Allenyl and Propargyl Complexes: An Experimental and Theoretical Study
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https://figshare.com/articles/dataset/Dinuclear_NHC_Gold_I_Allenyl_and_Propargyl_Complexes_An_Experimental_and_Theoretical_Study/7808786
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资源简介：
The
synthesis and isolation of the dinuclear NHC gold(I) allene-1,3-diyl
complex Ph(IPrAu)CCCH(AuIPr) and the dinuclear NHC
gold(I) propyne-1,3-diyl complex Ph(IPrAu)CH–CC–Au(IPr)
are presented. The monoprotodeauration reactions of these dinuclear
complexes selectively led to the mononuclear organogold complexes
Ph(IPrAu)CCCH2 and PhCH2–CC–Au(IPr),
respectively. The experimental structures and the obtained analytical
data of the synthesized complexes as well as the results of a computational
DFT study of their thermodynamic stability are compared systematically.
创建时间：
2019-03-06
