Divergent Synthesis of Functionalized Carbocycles through Organosilane-Directed Asymmetric Alkyne–Alkene Reductive Coupling and Annulation Sequence
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https://figshare.com/articles/dataset/Divergent_Synthesis_of_Functionalized_Carbocycles_through_Organosilane_Directed_Asymmetric_Alkyne_Alkene_Reductive_Coupling_and_Annulation_Sequence/2471374
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资源简介：
An organosilane-directed alkyne–alkene reductive
coupling
of readily available propargylsilanes is used to access densely functionalized
chiral allylsilanes. The divergent reactivity of the allylsilanes
can be controlled to afford a range of novel carbocyclic ring systems
through an intramolecular allylation, [3+2] annulation, and Sakurai-like
homodimerization.
创建时间：
2016-02-20
