Mollanol A, a Diterpenoid with a New C‑Nor-D-homograyanane Skeleton from the Fruits of Rhododendron molle
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https://figshare.com/articles/dataset/Mollanol_A_a_Diterpenoid_with_a_New_C_Nor_D_homo_grayanane_Skeleton_from_the_Fruits_of_Rhododendron_molle/2264410
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资源简介：
Two
new grayanoids, mollanol A (1) and rhodomollein XXV (2), were isolated from the fruits of Rhododendron
molle. Their structures were elucidated by spectroscopic
methods and X-ray diffraction analyses. Mollanol A (1) possesses a new C-nor-D-homograyanane carbon skeleton, while
rhodomollein XXV (2) is the first example of an 11,16-epoxygrayanane
and features a caged oxa-tricyclo[3.3.1.03.7]nonane ring
system. Plausible biogenetic pathways for 1 were proposed.
Compound 1 exhibited transcriptional activation effects
on the xbp1 upstream promoter in IEC-6, 293T, and
RAW264.7 cells.
创建时间：
2014-08-15
