Temperature-Dependent Enantio- and Diastereodivergent Synthesis of Amino Acids with One or Multiple Chiral Centers
收藏Figshare2017-08-15 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Temperature-Dependent_Enantio-_and_Diastereodivergent_Synthesis_of_Amino_Acids_with_One_or_Multiple_Chiral_Centers/5311834
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A general and facile methodology for temperature-dependent enantiodivergent and diastereodivergent synthesis of amino acids with one or multiple chiral centers was developed. Camphor-based tricyclic iminolactones attack electrophiles from the endo face at low temperature (−78 to −40 °C) and from the exo face at high temperature (−10 to 25 °C).
创建时间:
2017-08-15



