Synthesis of Alkynyl and Vinyl Selenides via Selenodecarboxylation of Arylpropiolic and Cinnamic Acids
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https://figshare.com/articles/dataset/Synthesis_of_Alkynyl_and_Vinyl_Selenides_via_Selenodecarboxylation_of_Arylpropiolic_and_Cinnamic_Acids/3253489
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资源简介：
The selenodecarboxylation of phenylpropiolic and cinnamic acid derivatives with diorgano
diselenide is promoted by iodosobenzene diacetate (PhI(OAc)2, IBDA) in acetonitrile at 30−60 °C, leading to the formation of alkynyl selenides and vinyl selenides in moderate to
excellent yields. Similar reactivity is also shown by iodosylbenzene (PhIO, IB). The reaction
is also triggered in the solid state. An electrophilic mechanism is proposed for the
transformation.
创建时间：
2016-05-05
