KLi(HC3N3O3)·2H2O: Solvent-drop Grinding Method toward the Hydro-isocyanurate Nonlinear Optical Crystal
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https://figshare.com/articles/dataset/KLi_HC_sub_3_sub_N_sub_3_sub_O_sub_3_sub_2H_sub_2_sub_O_Solvent-drop_Grinding_Method_toward_the_Hydro-isocyanurate_Nonlinear_Optical_Crystal/7719440
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A novel mixed alkali hydro-isocyanurate, KLi(HC3N3O3)·2H2O was first prepared in AOH-BOH-H3C3N3O3 (A/B = Li/Na/K/Rb/Cs) system via a solvent-drop grinding method. KLi(HC3N3O3)·2H2O shows a large second harmonic generation response (5.3 × KH2PO4) with an ultraviolet cutoff edge of 237 nm. More importantly, the bulk single crystal can be readily grown through water solution technique. Characterization of these crystals indicates that KLi(HC3N3O3)·2H2O has a high laser damage threshold (LDT) (4.76 GW/cm2) and exhibits a large birefringence (Δn = 0.186@514 nm), which reduces Type I phase-matching to 246 nm.
创建时间:
2019-02-14



