Reactivity of a Disilylene [{PhC(NBu<sup>t</sup>)<sub>2</sub>}Si]<sub>2</sub> toward Bromine: Synthesis and Characterization of a Stable Monomeric Bromosilylene
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The reaction of the disilylene [{PhC(NBut)2}Si]2 (1) with 1 equiv of bromine in toluene afforded novel monomeric bromosilylene [{PhC(NBut)2}SiBr] (2). The result shows that the SiI−SiI bond in 1 was cleaved by bromine. An X-ray structure of compound 2 has been determined.
创建时间：
2010-01-18
