Allylic Amination of Alkenes with Iminothianthrenes to Afford Alkyl Allylamines

Allylic C–H amination is currently accomplished with (sulfon)­amides or carbamates. Here we show the first allylic amination that can directly afford alkyl allylamines, enabled by the reactivity of thianthrene-based nitrogen sources that can be prepared from primary amines in a single step.