Aminolysis of Bis[bis(trimethylsilyl)amido]iron and -cobalt as a Versatile Route to N-Heterocyclic Carbene Complexes
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https://figshare.com/articles/dataset/Aminolysis_of_Bis_bis_trimethylsilyl_amido_iron_and_cobalt_as_a_Versatile_Route_to_N_Heterocyclic_Carbene_Complexes/2568883
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资源简介：
A range of new N-heterocyclic carbene complexes of iron(II)
and
cobalt(II) have been conveniently obtained by the aminolysis of bis[bis(trimethylsilyl)amido]iron
and -cobalt precursors with imidazol(in)ium salts. Whereas sterically
less hindered salts produced the tetrahedral complexes [M(carbene)2Cl2] (M = Fe), bulkier salts gave the three-coordinate
[M(carbene){N(SiMe3)2}Cl] (M = Fe, Co), which
serve as versatile precursors to a range of derivatives; mechanistic
aspects of the reaction are discussed.
创建时间：
2011-12-26
