Aminolysis of Bis[bis(trimethylsilyl)amido]iron and -cobalt as a Versatile Route to N-Heterocyclic Carbene Complexes
收藏NIAID Data Ecosystem2026-03-07 收录
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资源简介：
A range of new N-heterocyclic carbene complexes of iron(II) and cobalt(II) have been conveniently obtained by the aminolysis of bis[bis(trimethylsilyl)amido]iron and -cobalt precursors with imidazol(in)ium salts. Whereas sterically less hindered salts produced the tetrahedral complexes [M(carbene)2Cl2] (M = Fe), bulkier salts gave the three-coordinate [M(carbene){N(SiMe3)2}Cl] (M = Fe, Co), which serve as versatile precursors to a range of derivatives; mechanistic aspects of the reaction are discussed.
创建时间：
2011-12-26
