Rapid Synthesis of Polyprenylated Acylphloroglucinol Analogs via Dearomative Conjunctive Allylic Annulation
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https://figshare.com/articles/dataset/Rapid_Synthesis_of_Polyprenylated_Acylphloroglucinol_Analogs_via_Dearomative_Conjunctive_Allylic_Annulation/2038191
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资源简介：
Polyprenylated
acylphloroglucinols (PPAPs) are structurally complex
natural products with promising biological activities. Herein, we
present a biosynthesis-inspired, diversity-oriented synthesis approach
for rapid construction of PPAP analogs via double decarboxylative
allylation (DcA) of acylphloroglucinol scaffolds to access allyl-desoxyhumulones
followed by dearomative conjunctive allylic alkylation (DCAA).
创建时间：
2015-12-17
