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Small Cavitands Specifically Binding a Water Molecule

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NIAID Data Ecosystem2026-03-06 收录
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https://figshare.com/articles/dataset/Small_Cavitands_Specifically_Binding_a_Water_Molecule/3351103
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Three new C2v cavitands based on resorcin[4]arene bind water specifically at low temperature in CD2Cl2 or CDCl3 due to their complementarity to water as well as the solvophobic interaction. The averaged ΔH° and ΔS° values are −2.3 kcal mol-1 and −128 cal mol-1 K-1, which gave the averaged −ΔG° of 1.9 kcal mol-1 at −50 °C in water saturated CD2Cl2 .
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2016-05-07
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