Light-Driven Methyl Exchange Reactions in Square-Planar Palladium(II) and Platinum(II) Complexes
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https://figshare.com/articles/dataset/Light_Driven_Methyl_Exchange_Reactions_in_Square_Planar_Palladium_II_and_Platinum_II_Complexes/2312647
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资源简介：
Square-planar palladium(II) and platinum(II)
methyl complexes with
terpyridine and 6,6″-diamino terpyridine ligands undergo methyl exchange reactions
upon exposure to light. The half-life of the methyl exchange reactions
correlates with the relative Pd–C and Pt–C bond strengths.
No exchange between methyl and phenyl groups is observed, probably
due to the stronger Pt–C bond in the platinum phenyl complex.
A mechanism is proposed whereby a dinuclear intermediate is generated
upon irradiation that has a weakened M–C bond in the excited
state, resulting in the observed methyl exchange reactions.
创建时间：
2016-02-17
