Total Synthesis of (−)-Cinatrin C1 Based on an In(OTf)3‑Catalyzed Conia-Ene Reaction
收藏Figshare2016-02-19 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Total_Synthesis_of_Cinatrin_C_sub_1_sub_Based_on_an_In_OTf_sub_3_sub_Catalyzed_Conia_Ene_Reaction/2422408
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资源简介：
The stereocontrolled total synthesis of (−)-cinatrin C1, a phospholipase A2 inhibitor, has been accomplished. The key feature includes the stereoselective construction of the highly substituted tetrahydrofuran core by In(OTf)3-catalyzed Conia–ene reaction of the oxygen-tethered acetylenic malonic ester followed by dihydroxylation with concomitant lactonization.
创建时间：
2016-02-19
