Total Synthesis of (−)-Cinatrin C1 Based on an In(OTf)3‑Catalyzed Conia-Ene Reaction
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The stereocontrolled total synthesis of (−)-cinatrin C1, a phospholipase A2 inhibitor, has been accomplished. The key feature includes the stereoselective construction of the highly substituted tetrahydrofuran core by In(OTf)3-catalyzed Conia–ene reaction of the oxygen-tethered acetylenic malonic ester followed by dihydroxylation with concomitant lactonization.
创建时间：
2016-02-19
