Formation of a σ‑alkane Complex and a Molecular Rearrangement in the Solid-State: [Rh(Cyp<sub>2</sub>PCH<sub>2</sub>CH<sub>2</sub>PCyp<sub>2</sub>)(η<sup>2</sup>:η<sup>2</sup>‑C<sub>7</sub>H<sub>12</sub>)][BAr<sup>F</sup><sub>4</sub>]
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Addition of H2 to the precursor [Rh(Cyp2PCH2CH2PCyp2)(η2:η2-C7H8)][BArF4] gives the σ-alkane complex [Rh(Cyp2PCH2CH2PCyp2)(η2:η2-C7H12)][BArF4] by a single-crystal to single-crystal reaction, as characterized by X-ray crystallography, SSNMR spectroscopy, and periodic DFT. An unexpected rearrangement of the {Rh(L2)}+ fragment is revealed.
创建时间：
2016-10-27
