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Iodobenzene Catalyzed C–H Amination of N‑Substituted Amidines Using m‑Chloroperbenzoic Acid

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Figshare2016-02-19 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Iodobenzene_Catalyzed_C_H_Amination_of_i_N_i_Substituted_Amidines_Using_i_m_i_Chloroperbenzoic_Acid/2434111
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The oxidative C–H amination of N″-aryl-N′-tosyl/N′-methylsulfonylamidines and N,N′-bis(aryl)amidines has been accomplished using iodobenzene as a catalyst to furnish 1,2-disubstituted benzimidazoles in the presence of mCPBA as a terminal oxidant at room temperature. The reaction is general, and the target products can be obtained in moderate to high yields.
创建时间:
2016-02-19
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