Aluminum–Ligand Cooperative N–H Bond Activation and an Example of Dehydrogenative Coupling
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https://figshare.com/articles/dataset/Aluminum_Ligand_Cooperative_N_H_Bond_Activation_and_an_Example_of_Dehydrogenative_Coupling/2397187
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资源简介：
Activation of N–H
bonds by a molecular aluminum complex
via metal–ligand cooperation is described. (PhI2P2–)AlH (1b), in which PhI2P2– is a tridentate bis(imino)pyridine
ligand, reacts with anilines to give the N–H-activated products
(PhHI2P–)AlH(NHAr) (2). When heated, 2 releases H2 and
affords (PhI2P–)Al(NHAr) (3). Complex 1b catalyzes the dehydrogenative
coupling of benzylamine to afford H2, NH3, and N-(phenylmethylene)benzenemethanamine.
创建时间：
2016-02-19
