A Dihalide–Decahydrate Cluster of [X2(H2O)10]2– in a Supramolecular Architecture of {[Na2(H2O)6(H2O@TMEQ[6])]·2(C6H5NO3)}X2(H2O)10 (TMEQ[6] = α,α′,δ,δ′-Tetramethylcucurbit[6]uril; X = Cl, Br)
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https://figshare.com/articles/dataset/A_Dihalide_Decahydrate_Cluster_of_X_sub_2_sub_H_sub_2_sub_O_sub_10_sub_sup_2_sup_in_a_Supramolecular_Architecture_of_Na_sub_2_sub_H_sub_2_sub_O_sub_6_sub_H_sub_2_sub_O_TMEQ_6_2_C_sub_6_sub_H_sub_5_sub_NO_sub_3_sub_X_sub_2_sub_H_sub_2_sub_O_sub_10_sub_TMEQ/2560039
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A discrete dihalide–decahydrate cluster of [X2(H2O)10]2– has been observed in a solid-state structure of {[Na2(H2O)6(H2O@TMEQ[6])]·2(C6H5NO3)}X2(H2O)10} (TMEQ[6] = α,α′,δ,δ′-tetramethylcucurbit[6]uril; X = Cl (1), Br (2)). Its structure can be viewed as a connection of two [X(H2O)3]− clusters with a uudd water tetramer through hydrogen-bonding interactions.
创建时间：
2016-02-22
