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Pentadecatungstate with Dinuclear Cerium(III) Unit: Synthesis, Crystal Structure and Properties

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https://figshare.com/articles/dataset/Pentadecatungstate_with_Dinuclear_Cerium_III_Unit_Synthesis_Crystal_Structure_and_Properties/2929267
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资源简介:
A novel pentadecatungstate, [H6Ce2(H2O)Cl(W5O18)3]7− (1), constructed by a dinuclear cerium unit and 15-member ring WO6 units was prepared and characterized by single-crystal X-ray diffraction. Polyanion 1 exhibits blue photoluminescence with an emission maximum at 488 nm, which is characteristic of cerium(III) transitions from 5d to 2F5/2 states. Furthermore, the study of the electrochemical property investigation of 1 shows two reversible redox peaks ascribing to two-electron processes.
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2016-02-27
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