Syntheses, Crystal Structures, and Properties of Four Metal–Organic Complexes Based on 1,4,5,6,7,7-Hexachlorobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic Acid
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https://figshare.com/articles/dataset/Syntheses_Crystal_Structures_and_Properties_of_Four_Metal_Organic_Complexes_Based_on_1_4_5_6_7_7_Hexachlorobicyclo_2_2_1_hept_5_ene_2_3_dicarboxylic_Acid/2200564
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资源简介：
Four metal–organic
complexes [Ni(HET)(phen)(H2O)]·(HET)·H2O (1), [Cu(HET)(phen)(H2O)]·1.5H2O (2), [Cu2(HET)2(bipy)1.5(H2O)]·15DMF·2H2O (3), and [Cd2O(HET)2(bipy)(H2O)]·2H2O·EtOH (4) (HET = 1,4,5,6,7,7-hexachlorobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic
acid, phen = 1,10-phenanthroline, bipy = 4,4′-bipyridine) have
been synthesized via hydro- or solvothermal reactions. It was found
that complexes 1 and 2 are two-dimensional
(2D) structures built from discrete complexes via the typical intermolecular
interactions, and there was a closed loop built from the lattice water
and carboxylate groups in 1 through intramolecular hydrogen
bonds. Complex 3 exhibits three-dimensional (3D) structure
with 5-connected bnn hexagonal BN topology.
Complex 4 features a non-interpenetrating sql 2D coordination network, which is further linked
into a 3D structure by C–H···Cl weak interaction.
The properties of magnetism, fluorescence, and electrochemistry have
also been investigated in this paper.
创建时间：
2016-02-15
