Materials Data on TmPPd by Materials Project

TmPdP crystallizes in the orthorhombic Pnma space group. The structure is three-dimensional. Tm is bonded in a 5-coordinate geometry to six equivalent Pd and five equivalent P atoms. There are a spread of Tm–Pd bond distances ranging from 3.01–3.25 Å. There are a spread of Tm–P bond distances ranging from 2.81–2.89 Å. Pd is bonded to six equivalent Tm, two equivalent Pd, and four equivalent P atoms to form a mixture of distorted face, edge, and corner-sharing PdTm6P4Pd2 cuboctahedra. Both Pd–Pd bond lengths are 2.99 Å. There are a spread of Pd–P bond distances ranging from 2.53–2.76 Å. P is bonded in a 9-coordinate geometry to five equivalent Tm and four equivalent Pd atoms.