Self-Assembled Containers Based on Extended Tetrathiafulvalene
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https://figshare.com/articles/dataset/Self_Assembled_Containers_Based_on_Extended_Tetrathiafulvalene/2397244
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Two original self-assembled containers constituted each by six electroactive subunits are described. They are synthesized from a concave tetratopic π-extended tetrathiafulvalene ligand bearing four pyridyl units and cis-M(dppf)(OTf)2 (M = Pd or Pt; dppf = 1,1′-bis(diphenylphosphino)ferrocene; OTf = trifluoromethane-sulfonate) complexes. Both fully characterized assemblies present an oblate spheroidal cavity that can incorporate one perylene molecule.
创建时间:
2016-02-19



