MOFs基催化剂的设计合成及应用

MOFs基催化剂的设计合成及应用研究数据是由华南大学化学与化工学院提供的有关非均相MOFs基催化剂催化的有机反应的研究原始数据，主要记录了手性Cu (salen)基金属有机骨架合成后还原修饰增强Henry反应的活性和对映选择性、用于CO2转化和不对称C-H叠氮化的高度稳定的手性Zr-MOFs、稳定的金属-有机框架负载钯催化剂用于有氧氧化系统、用于醛的不对称氰基硅烷化的基于卟啉-salen的手性金属-有机骨架、一种具有高热稳定性、水性稳定性和化学稳定性的手性salen-MOF 催化材料、完全间位取代的 4,4'-联苯二羧酸盐基金属有机骨架：合成、结构和催化活性、、Ni(salen)基金属-有机骨架：CO2环加成反应的合成、结构和催化性能、通过基于单晶向单晶转化的后合成金属化开发同构卟啉-Salen手性金属-有机骨架、一种负载双活性位点的锆基MOFs催化剂的制备方法等反应中的数据（包括MOFs及催化剂的XRD、BET、SEM、TEM、XPS、核磁数据，红外数据等）

The research data on the design, synthesis and application of MOFs-based catalysts, provided by the School of Chemistry and Chemical Engineering, University of South China, are original experimental data focused on heterogeneous MOFs-catalyzed organic reactions. The data mainly cover the following contents: reductive modification of chiral Cu(salen)-based metal-organic frameworks after synthesis to enhance the activity and enantioselectivity of Henry reaction; highly stable chiral Zr-MOFs used for CO₂ conversion and asymmetric C-H azidation; stable metal-organic framework-supported palladium catalysts applied in aerobic oxidation systems; porphyrin-salen-based chiral metal-organic frameworks for asymmetric cyanosilylation of aldehydes; a chiral salen-MOF catalytic material with high thermal stability, aqueous stability and chemical stability; fully meta-substituted 4,4'-biphenyldicarboxylate-based metal-organic frameworks: synthesis, structure and catalytic activity; Ni(salen)-based metal-organic frameworks: synthesis, structure and catalytic performance for CO₂ cycloaddition reaction; development of isostructural porphyrin-salen chiral metal-organic frameworks via post-synthetic metallization based on single-crystal to single-crystal transformation; preparation method of a zirconium-based MOFs catalyst loaded with dual active sites, and other related reaction data. The collected data include the characterization data of MOFs and catalysts, such as XRD, BET, SEM, TEM, XPS, nuclear magnetic resonance data, infrared data and other test data.

搜集汇总

背景与挑战

背景概述

该数据集由华南理工大学提供，专注于MOFs基催化剂的设计、合成及应用研究，包含非均相催化剂催化的有机反应原始数据，如Henry反应、CO2转化等，涵盖XRD、BET、SEM等多种实验数据，数据量达2.12GB（2878个文件）。数据集支持有机合成化学领域的研究，源自国家重点研发计划项目，旨在促进低碳与绿色化工医药途径的发展。