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Borole-Derived Spirocyclic Tetraorganoborate

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Figshare2016-02-20 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Borole_Derived_Spirocyclic_Tetraorganoborate/2461978
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Preparation of a novel conjugated tetraorganoborate is presented in a facile two-step procedure. Successful utilization as a halide abstraction reagent is demonstrated in a metathesis reaction with the platinum­(II) boryl complex [(Cy3P)2Pt­(Br)­(BC4Ph4)], which was obtained by oxidative addition of 1-bromo-2,3,4,5-tetraphenylborole to a platinum(0) species. The novel compounds were investigated by means of spectroscopic and X-ray diffraction techniques.
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2016-02-20
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