A Chiral Ruthenium-Monophosphine Catalyst for Asymmetric Addition of Arylboronic Acids to Aryl Aldehydes
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https://figshare.com/articles/dataset/A_Chiral_Ruthenium_Monophosphine_Catalyst_for_Asymmetric_Addition_of_Arylboronic_Acids_to_Aryl_Aldehydes/2403193
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A novel ruthenium catalyst on the basis of a chiral monophosphorus ligand is efficient for the asymmetric addition of arylboronic acids to aryl aldehydes, providing a series of chiral diarylmethanols in excellent yields and enantioselectivities (up to 92% ee). Preliminary study has shown that this process is catalyzed by a Ru complex with a single monophosphorus ligand.
创建时间:
2016-02-19



