Ni work

Nickel supported on η-Al₂O₃ and ZSM-5(80) catalysts with and without the addition of ceria-zirconia, were prepared by co-precipitation and wet impregnation methods and used for the low temperature catalytic partial oxidation of methane (CPOM). The catalysts were tested under reaction temperatures of between 400 and 700 °C with a WHSV of 63,000 mL g^-1 h^-1. The activity of the catalyst was found to be dependent on the support and preparation method. The optimum catalyst composition of those tested was 10% Ni on 25ÎO₂-ZrO₂/ZSM-5(80), prepared by co-precipitation, where the reaction reached equilibrium conversion at 400 °C (T_50%< 400 °C), which is one of the lowest temperatures reported to date. Further increases in temperature led to improved selectivity to CO reaching 60% at 600 °C. Although the observed kinetics were found to be controlled by strong adsorption of CO at lower temperature, this was an equilibrium limitation with longer time on stream experiments showing no decrease in the catalyst activity over 25 hours at 400 °C.