five

Interesting Anion-Inclusion Behavior of Cucurbit[5]uril and Its Lanthanide-Capped Molecular Capsule

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NIAID Data Ecosystem2026-03-06 收录
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https://figshare.com/articles/dataset/Interesting_Anion_Inclusion_Behavior_of_Cucurbit_5_uril_and_Its_Lanthanide_Capped_Molecular_Capsule/2972467
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The selective encapsulation behavior of cucurbit [5]uril and its lanthanide-capped molecular capsule toward nitrate and chloride ions has been investigated. Using fluorescence spectroscopy, the metal-free host has been demonstrated to selectively include nitrate ion. In contrast, the lanthanide-capped molecular capsule showed preference toward the inclusion of chloride ion. Solid-state structures of the nitrate and chloride inclusion complexes with the La(III)-capped molecular capsule have been crystallographically determined.
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2016-06-03
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