Total Synthesis of (−)-Nahuoic Acid Ci (Bii)
收藏Figshare2017-09-21 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Total_Synthesis_of_-Nahuoic_Acid_C_sub_i_sub_B_sub_ii_sub_/5427394
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资源简介：
A convergent total synthesis of (−)-nahuoic acid Ci(Bii) (3), a novel cis-decalin polyketide, has been achieved. Key synthetic transformations include Type II Anion Relay Chemistry (ARC) to construct the polyol chain, a Ti-catalyzed asymmetric Diels–Alder reaction to generate the cis-decalin skeleton, and a late-stage large fragment union exploiting a Micalizio alkoxide-directed alkyne–alkene coupling tactic.
创建时间：
2017-09-21
