Total Synthesis of (±)-Aplykurodinone-1: Traceless Stereochemical Guidance
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https://figshare.com/articles/dataset/Total_Synthesis_of_Aplykurodinone_1_Traceless_Stereochemical_Guidance/2750665
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资源简介：
The total synthesis of the highly degraded steroidal natural product, aplykurodinone-1 (1), has been accomplished. Key features include a one-flask hydrolysis/retro-aldol/iodolactonization sequence to excise the C8 hydroxymethylene functionality with retention of stereochemistry and the stereoselective installation of the C13 methyl group through hydrogenation with homogeneous catalyst.
创建时间：
2016-02-24
