Total Synthesis of (±)-Hirsutine: Application of Phosphine-Catalyzed Imine–Allene [4 + 2] Annulation
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https://figshare.com/articles/dataset/Total_Synthesis_of_Hirsutine_Application_of_Phosphine_Catalyzed_Imine_Allene_4_2_Annulation/2489806
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资源简介：
The total synthesis of the indole alkaloid hirsutine has been achieved, with a key step being the application of our phosphine-catalyzed [4 + 2] annulation of an imine with ethyl α-methylallenoate. From commercially available indole-2-carboxaldehyde, the target was synthesized in 14 steps and 6.7% overall yield.
创建时间：
2012-09-07
