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Synthesis and Characterization of a Coordinated Oxoborane: Lewis Acid Stabilization of a Boron−Oxygen Double Bond

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NIAID Data Ecosystem2026-03-06 收录
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https://figshare.com/articles/dataset/Synthesis_and_Characterization_of_a_Coordinated_Oxoborane_Lewis_Acid_Stabilization_of_a_Boron_Oxygen_Double_Bond/3292597
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The first example of a stable oxoborane monomer (LBO) stabilized by complexation to AlCl3 has been prepared by the reaction of LAlCl2 with BCl3 followed by treatment with H2O in CH2Cl2 (L = [HC(CMe)2(NC6F5)2]). DFT calculations reveal that considerable boron−oxygen double bond character is retained in this complex.
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2016-05-06
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